CN 41-1243/TG ISSN 1006-852X
Volume 44 Issue 2
Apr.  2024
Turn off MathJax
Article Contents
ZOU Qin, DONG Peihang, LI Yanguo, YUAN Zhenxiong, WU Di, LUO Yongan. Effects of the ratio of binder and the ratio of cBN particle size on the microstructure and properties of PcBN composites[J]. Diamond & Abrasives Engineering, 2024, 44(2): 185-192. doi: 10.13394/j.cnki.jgszz.2023.0090
Citation: ZOU Qin, DONG Peihang, LI Yanguo, YUAN Zhenxiong, WU Di, LUO Yongan. Effects of the ratio of binder and the ratio of cBN particle size on the microstructure and properties of PcBN composites[J]. Diamond & Abrasives Engineering, 2024, 44(2): 185-192. doi: 10.13394/j.cnki.jgszz.2023.0090

Effects of the ratio of binder and the ratio of cBN particle size on the microstructure and properties of PcBN composites

doi: 10.13394/j.cnki.jgszz.2023.0090
More Information
  • Received Date: 2023-04-16
  • Accepted Date: 2023-11-07
  • Rev Recd Date: 2023-09-13
  • Available Online: 2023-11-07
  • Polycrystalline cubic boron nitride composites were prepared under high-temperature and high-pressure conditions. The effects of bonding agent ratio and cBN particle size on the composition, microstructure, microhardness, and abrasive ratios of the PcBN composites were investigated using X-ray diffraction (XRD), field scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The experimental results showed that the PcBN composites performed better under sintering conditions of 5.5 GPa, 1400 ℃, and a 10-minute holding time, achieving a hardness of up to 22.7 GPa and an abrasion ratio of 149.2 at V(TiN0.3)∶V(AlN)=70∶30. Moreover, when the particle size combination of cBN in PcBN composites is (0.5~1) μm:(2~5) μm:(5~10) μm = 3:5:2, the packing density between particles reaches its peak, resulting in optimal performance.


  • loading
  • [1]
    WANG W J, LI Z H, ZHU Y M, et al. Effect of diamond additive on the properties of cBN composites with Al–Si as binder by HTHP sintering [J]. Ceramics International,2022,48(19):28830-28834. doi: 10.1016/j.ceramint.2022.03.028
    WANG S Y, LI Z H, ZHU Y M, et al. Enhanced mechanical properties of cBN-Al-Si3N4 composites by introducing diamond [J]. Diamond and Related Materials,2022,121:108808. doi: 10.1016/j.diamond.2021.108808
    CHEN L, STAHL J E, ZHAO W, et al. Assessment on abrasiveness of high chromium cast iron material on the wear performance of PCBN cutting tools in dry machining [J]. Journal of Materials Processing Technology,2018,255:110-120. doi: 10.1016/j.jmatprotec.2017.11.054
    KUMAR R, ANTONOV M, KLIMCZYK P, et al. Effect of cBN content and additives on sliding and surface fatigue wear of spark plasma sintered Al2O3-cBN composites [J]. Wear,2022(494/495):204250. doi: 10.1016/j.wear.2022.204250
    JI H L, LI Z H, LIU M. Structural and mechanical properties of cBN composites by regulating particle size distribution and holding time [J]. International Journal of Refractory Metals and Hard Materials,2021,100:105635. doi: 10.1016/j.ijrmhm.2021.105635
    LIU Y, SUN A L, ZHONG S L, et al. Effect of Al Ti content on mechanical properties of in-situ synthesized PcBN composites [J]. Diamond and Related Materials,2020,109:108068. doi: 10.1016/j.diamond.2020.108068
    ZOU Q, WU H Y, LI Y G, et al. Effects of carbon nanotubes and sintering parameters on microstructure and properties of PCD [J]. Diamond and Related Materials,2022,128:109293. doi: 10.1016/j.diamond.2022.109293
    MO P C, CHEN C, JIA G, et al. Effect of tungsten content on microstructure and mechanical properties of PCBN synthesized in cBN-Ti-Al-W system [J]. International Journal of Refractory Metals and Hard Materials,2020,87:105138. doi: 10.1016/j.ijrmhm.2019.105138
    SLIPCHENKO K, BUSHLYA V, STRATIICHUK D, et al. Multicomponent binders for PcBN performance enhancement in cutting tool applications [J]. Journal of the European Ceramic Society,2022,42(11):4513-4527. doi: 10.1016/j.jeurceramsoc.2022.04.022
    陈俊云, 孙磊, 靳田野, 等. 无黏结剂层状BN增韧cBN刀具材料的研究 [J]. 无机材料学报,2022,37(6):623-628. doi: 10.15541/jim20210300

    CHEN Junyun, SUN Lei, JIN Tianye, et al. Binderless layered BN toughened cBN for ultra-precision cutting [J]. Journal of Inorganic Materials,2022,37(6):623-628. doi: 10.15541/jim20210300
    CHEN S, FAN H Z, SU Y F, et al. Influence of binder systems on sintering characteristics, microstructures, and mechanical properties of PcBN composites fabricated by SPS [J]. Journal of Advanced Ceramics,2022,11(2):321-330. doi: 10.1007/s40145-021-0536-4
    GORDON S, ROA J J, RODRIGUEZ-SUAREZ T, et al. Influence of microstructural assemblage of the substrate on the adhesion strength of coated PcBN grades [J]. Ceramics International,2022,48(15):22354-22363. doi: 10.1016/j.ceramint.2022.04.236
    王艳芝, 张旺玺, 孙长红, 等. 氮化硼系列材料的合成制备及应用研究进展 [J]. 陶瓷学报,2018,39(6):661-671. doi: 10.13957/j.cnki.tcxb.2018.06.002

    WANG Yanzhi, ZHANG Wangxi, SUN Changhong, et al. The development of the applications and synthesis of boron nitride materials [J]. Journal of Ceramics,2018,39(6):661-671. doi: 10.13957/j.cnki.tcxb.2018.06.002
    CHEN C, MO P C, CHEN J R, et al. Effects of different binder systems on the reaction mechanism, microstructure and mechanical properties of PcBN composites [J]. Diamond and Related Materials,2023,134:109797. doi: 10.1016/j.diamond.2023.109797
    邓华, 潘天浩, 张志超, 等. 共价键化合物陶瓷结合剂对干切削PcBN刀具复合材料的影响 [J]. 超硬材料工程,2017,29(3):1-12. doi: 10.3969/j.issn.1673-1433.2017.03.001

    DENG Hua, PAN Tianhao, ZHANG Zhichao, et al. The influence of covalent compound ceramic bond on composite materials of PcBN cutting tools for drycutting [J]. Superhard Material Engineering,2017,29(3):1-12. doi: 10.3969/j.issn.1673-1433.2017.03.001
    CHU D L, MA H G, ZHANG Z F, et al. Synthesis and characterization of cubic boron nitride (Al)-Al2O3 composites under high pressure and high temperature conditions [J]. International Journal of Refractory Metals and Hard Materials,2022,106:105876. doi: 10.1016/j.ijrmhm.2022.105876
    梁宝岩, 张旺玺, 冯燕翔, 等. 立方氮化硼用量及粒度对其同钛铝碳结合剂的反应程度的影响 [J]. 金刚石与磨料磨具工程,2016,36(5):38-41. doi: 10.13394/j.cnki.jgszz.2016.5.0007

    LIANG Baoyan, ZHANG Wangxi, FENG Yanxiang, et al. Fabrication and microstructure analys is of Ti3AlC2-CBN composites [J]. Diamond & Abrasives Engineering,2016,36(5):38-41. doi: 10.13394/j.cnki.jgszz.2016.5.0007
    WANG H, DENG F M, ZHANG Z W, et al. Study on the properties and fracture mode of pure polycrystalline cubic boron nitride with different particle sizes [J]. International Journal of Refractory Metals and Hard Materials,2021,95:105446. doi: 10.1016/j.ijrmhm.2020.105446
    范文捷, 刘芳, 董艳丽. CBN粒度及组装方式对PCBN性能影响的研究 [J]. 金刚石与磨料磨具工程,2009,4(2):67-73. doi: 10.13394/j.cnki.jgszz.2009.02.017

    FAN Wenjie, LIU Fang, DONG Yanli. Effect of grain size of CBN and ssemblmodeon characteristics of PCBN [J]. Diamond & Abrasives Engineering,2009,4(2):67-73. doi: 10.13394/j.cnki.jgszz.2009.02.017
    WU J K, ZHANG Z C, WANG H K, et al. High-pressure synthesis of tungsten carbide–cubic boron nitride (WC–cBN) composites: Effect of cBN particle size and volume fraction on their microstructure and properties [J]. International Journal of Refractory Metals and Hard Materials,2023,110:106037. doi: 10.1016/j.ijrmhm.2022.106037
    XU S, WANG M Z, QIAO L N, et al. Enhancing the sintering ability of TiNx by introduction of nitrogen vacancy defects [J]. Ceramics International,2015,41(8):9514-9520. doi: 10.1016/j.ceramint.2015.04.009
    苏君, 杨帆. 烧结助剂含量对PcBN复合材料显微结构和力学性能的影响 [J]. 中国陶瓷,2022,58(2):32-36. doi: 10.16521/j.cnki.issn.1001-9642.2022.02.005

    SU Jun, YANG Fan. Effect of sintering intering content on microstructure and mechanical property of PcBN composites [J]. China Ceramics,2022,58(2):32-36. doi: 10.16521/j.cnki.issn.1001-9642.2022.02.005
    WANG Z W, LI Y G, ZOU Q, et al. Effect of sintering parameters on microstructure and properties of nanopolycrystalline diamond bulks synthesized from onion-like carbon [J]. Diamond and Related Materials,2021,111:108233. doi: 10.1016/j.diamond.2020.108233
    陈超, 莫培程, 林峰, 等. cBN-TiN-Al合成PcBN复合片及其性能研究 [J]. 中国陶瓷,2019,55(7):36-41. doi: 10.16521/j.cnki.issn.1001-9642.2019.07.006

    CHEN Chao, MO Peicheng, LIN Feng, et al. Synthesis of PcBN composite by cBN-TiN-Al and performance research [J]. China Ceramics,2019,55(7):36-41. doi: 10.16521/j.cnki.issn.1001-9642.2019.07.006
    邓华, 邢英, 王明智, 等. PcBN烧结体中TiN0.3/AlN与cBN的界面关系研究 [J]. 金刚石与磨料磨具工程,2016,36(3):38-42. doi: 10.13394/j.cnki.jgszz.2016.3.0008

    DENG Hua, XING Ying, WANG Mingzhi, et al. Research on the interface relation between TiN0.3/AlN and cBN in PcBN sintering body [J]. Diamond & Abrasives Engineering,2016,36(3):38-42. doi: 10.13394/j.cnki.jgszz.2016.3.0008
    谢辉, 冯飞, 方海江, 等. 不同组分cBN-TiC-Al材料对PcBN性能的影响 [J]. 金刚石与磨料磨具工程,2013,33(1):31-35. doi: 10.13394/j.cnki.jgszz.2013.01.010

    XIE Hui, FENG Fei, FANG Haijiang, et al. Influence of ratios of cBN-TiC-Al on PCBN properties [J]. Diamond & Abrasives Engineering,2013,33(1):31-35. doi: 10.13394/j.cnki.jgszz.2013.01.010
    李工, 戴凤祥, 张翼飞, 等. Al系高熵合金高温氧化性能研究进展 [J]. 燕山大学学报,2021,45(3):189-201. doi: 10.3969/j.issn.1007-791X.2021.03.001

    LI Gong, DAI Fengxiang, ZHANG Yifei, et al. Research progress of high-temperture oxidation properties of Al-based high entropy alloys [J]. Journal of Yanshan University,2021,45(3):189-201. doi: 10.3969/j.issn.1007-791X.2021.03.001
    邹芹, 李园园, 李艳国. 铁基自润滑复合材料增强的研究进展与展望 [J]. 燕山大学学报,2021,45(5):377-386. doi: 10.3969/j.issn.1007-791X.2021.05.001

    ZOU Qin, LI Yuanyuan, LI Yanguo. Progress and prospect of iron-based self-lubricating composites reinforcement [J]. Journal of Yanshan University,2021,45(5):377-386. doi: 10.3969/j.issn.1007-791X.2021.05.001
    邹芹, 关勇, 李艳国, 等. TiAl合金及其复合材料的研究进展与发展趋势 [J]. 燕山大学学报,2020,44(2):95-107. doi: 10.3969/j.issn.1007-791X.2020.02.001

    ZOU Qin, GUAN Yong, LI Yanguo, et al. Advances and perspectives of TiAl alloy and its composites [J]. Journal of Yanshan University,2020,44(2):95-107. doi: 10.3969/j.issn.1007-791X.2020.02.001
    XU S, WANG M Z, QIAO L N, et al. Influence of nitrogen vacancy defects incorporation on densification behaviour of spark plasma sintered non-stoichiometric TiN1−x [J]. Advances in applied ceramics,2015,114(5):256-260. doi: 10.1179/1743676114Y.0000000216
    韦家新, 林峰, 冯吉福. 影响立方氮化硼复合片耐磨性的工艺因素研究 [J]. 超硬材料工程,2006(3):16-18.

    WEI Jiaxin, LIN Feng, FENG Jifu. Technological factors influencing wear resistance of PCBN [J]. Superhard Material Engineering,2006(3):16-18.
    ZOU Q, DONG P H, LI Y G, et al. Preparation and characterization of PcBN composites with high entropy ceramic bonding [J]. Diamond and Related Materials,2023,131:109536. doi: 10.1016/j.diamond.2022.109536
    张立, 王喆, 陈述, 等. 过渡族金属碳化物在WC-Co硬质合金中的界面偏析与固溶行为 [J]. 硬质合金,2014,31(1):49-59.

    ZHANG LI, WANG Zhe, CHEN Shu, et al. Boundary segregation and solid solution behaviors of transitional metal carbides in WC-Co cemented carbides [J]. Cemented Carbides,2014,31(1):49-59.
    邹芹, 李壮, 李艳国, 等. 中熵碳化物陶瓷TiC0.4/VC/NbC结合的WC基硬质合金合成与性能 [J]. 中国有色金属学报,2022,6(33):1914-1923. doi: 10.11817/j.ysxb.1004.0609.2022-43353

    ZOU Qin, LI Zhang, LI Yanguo, et al. Synthesis and properties of WC-based cemented carbide combined with TiC0.4/VC/NbC medium entropy carbide ceramics [J]. The Chinese Journal of Nonferrous Metals,2022,6(33):1914-1923. doi: 10.11817/j.ysxb.1004.0609.2022-43353
  • 加载中


    通讯作者: 陈斌,
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(7)  / Tables(2)

    Article Metrics

    Article views (265) PDF downloads(17) Cited by()
    Proportional views


    DownLoad:  Full-Size Img  PowerPoint