CN 41-1243/TG ISSN 1006-852X
Volume 42 Issue 2
May  2022
Turn off MathJax
Article Contents
WANG Chuqi, KOU Zili. A review of preparing binderless PcBN at high temperature and high pressure[J]. Diamond &Abrasives Engineering, 2022, 42(2): 162-168. doi: 10.13394/j.cnki.jgszz.2021.0409
Citation: WANG Chuqi, KOU Zili. A review of preparing binderless PcBN at high temperature and high pressure[J]. Diamond &Abrasives Engineering, 2022, 42(2): 162-168. doi: 10.13394/j.cnki.jgszz.2021.0409

A review of preparing binderless PcBN at high temperature and high pressure

doi: 10.13394/j.cnki.jgszz.2021.0409
  • Received Date: 2021-04-09
  • Accepted Date: 2022-03-09
  • Rev Recd Date: 2022-01-21
  • Polycrytalline cubic boron nitride, PcBN for short, has the advantages of large size, isotropy and no cleavage plane so that it is widely used. Commercial PcBNs are generally sintered with binders to reduce sintering conditions to pressures ranging from 5.5 to 7.7 GPa and temperatures of 1600 to 2300 K. However, binders reduce the performance of the product, Vickers hardness ranging from 22 to 45 GPa for example. Based on the fact that the material itself is the best binder, pure phase PcBNs were prepared by four different initial materials, the sintering behavior and the properties of which were introduced and evaluated. In conclusion, the pure phase PcBN material with good performance can be prepared by using cBN as the initial material and adopting related processes.

     

  • loading
  • [1]
    WENTORF R H. Cubic form of boron nitride [J]. The Journal of Chemical Physics,1957,26(4):956.
    [2]
    YANG D, JI X, LIU H, et al. The influence of Li-based catalysts / additives on cBN crystal morphologies synthesized under HPHT [J]. Diamond and Related Materials,2011,20(2):174-177. doi: 10.1016/j.diamond.2010.11.023
    [3]
    吉晓瑞, 苏作鹏, 杜勇慧, 等. 化学反应直接成核生长立方氮化硼 [J]. 金刚石与磨料磨具工程,2007(4):25-26. doi: 10.3969/j.issn.1006-852X.2007.04.007

    JI Xiaorui, SU Zuopeng, DU Yonghui, et al. Studies about the growth of cBN nucleated directly by chemical reaction [J]. Diamond and Abrasives Engineering,2007(4):25-26. doi: 10.3969/j.issn.1006-852X.2007.04.007
    [4]
    KO E H, KIM T H, CHOI S, et al. Synthesis of cubic boron nitride nanoparticles from boron oxide, melamine and NH3 by non-transferred Ar-N2 thermal plasma [J]. Journal of Nanoscience and Nanotechnology,2015,15(11):8515-8520. doi: 10.1166/jnn.2015.11469
    [5]
    BEASON M T, PAULS J M, GUNDUZ I E, et al. Shock-induced reaction synthesis of cubic boron nitride [J]. Applied Physics Letters,2018,112(17):171903. doi: 10.1063/1.5017836
    [6]
    BUNDY F P, WENTORF R H. Direct transformation of hexagonal boron nitride to denser forms [J]. The Journal of Chemical Physics,1963,38(5):1144-1149. doi: 10.1063/1.1733815
    [7]
    CORRIGAN F R, BUNDY F P. Direct transitions among the allotropic forms of boron nitride at high pressures and temperatures [J]. The Journal of Chemical Physics,1975,63(9):3812-3820. doi: 10.1063/1.431874
    [8]
    WAKATSUKI M, ICHINOSE K, AOKI T. Synthesis of polycrystalline cubic BN [J]. Materials Research Bulletin,1972,7(9):999-1003. doi: 10.1016/0025-5408(72)90091-8
    [9]
    AKAISHI M, SATOH T, ISHII M, et al. Synthesis of translucent sintered cubic boron nitride [J]. Journal of Materials Science Letters,1993,12(24):1883-1885. doi: 10.1007/BF00882529
    [10]
    TANIGUCHI T, AKAISHI M, YAMAOKA S. Mechanical properties of polycrystalline translucent cubic boron nitride as characterized by the Vickers indentation method [J]. Journal of the American Ceramic Society,1996,79(2):547-549. doi: 10.1111/j.1151-2916.1996.tb08165.x
    [11]
    OHASHI T, YAMAMOTO K, HAMADA Y, et al. Some properties and cutting performance of polycrystalline cubic boron nitride with no additives [J]. International Journal of Refractory Metals and Hard Materials,1998,16(4/5/6):403-407. doi: 10.1016/S0263-4368(98)00057-2
    [12]
    SUMIYA H, UESAKA S, SATOH S. Mechanical properties of high purity polycrystalline cBN synthesized by direct conversion sintering method [J]. Journal of Materials Science,2000,35(5):1181-1186. doi: 10.1023/A:1004780218732
    [13]
    YANG M, KOU Z L, LIU T, et al. Polycrystalline cubic boron nitride prepared with cubic-hexagonal boron nitride under high pressure and high temperature [J]. Chinese Physics B,2018,27(5):056105. doi: 10.1088/1674-1056/27/5/056105
    [14]
    DUB S N, PETRUSHA I A. Mechanical properties of polycrystalline cBN obtained from pyrolytic gBN by direct transformation technique [J]. High Pressure Research,2006,26(2):71-77. doi: 10.1080/08957950600764239
    [15]
    DUBROVINSKAIA N, SOLOZHENKO V L, MIYAJIMA N, et al. Superhard nanocomposite of dense polymorphs of boron nitride: Noncarbon material has reached diamond hardness [J]. Applied Physics Letters,2007,90(10):101912. doi: 10.1063/1.2711277
    [16]
    SOLOZHENKO V L, KURAKEVYCH O O, Le GODEC Y. Creation of nanostuctures by extreme conditions: High‐pressure synthesis of ultra- hard nanocrystalline cubic boron nitride [J]. Advanced Materials,2012,24(12):1540-1544. doi: 10.1002/adma.201104361
    [17]
    ICHIDA Y, OHFUJI H, IRIFUNE T, et al. Synthesis of ultrafine nano-polycrystalline cubic boron nitride by direct transformation under ultrahigh pressure [J]. Journal of the European Ceramic Society,2018,38(7):2815-2822. doi: 10.1016/j.jeurceramsoc.2018.02.023
    [18]
    TIAN Y, XU B, YU D, et al. Ultrahard nanotwinned cubic boron nitride [J]. Nature,2013,493(7432):385-388. doi: 10.1038/nature11728
    [19]
    DUBROVINSKAIA N, DUBROVINSKY L. Controversy about ultrahard nanotwinned cBN [J]. Nature,2013,502(7472):E1-E2. doi: 10.1038/nature12620
    [20]
    TANIGUCHI T, AKAISHI M, YAMAOKA S. Sintering of cubic boron nitride without additives at 7.7 GPa and above 2 000 ℃ [J]. Journal of Materials Research,1999,14(1):162-169. doi: 10.1557/JMR.1999.0024
    [21]
    LIU G, KOU Z, YAN X, et al. Submicron cubic boron nitride as hard as diamond [J]. Applied Physics Letters,2015,106(12):121901. doi: 10.1063/1.4915253
    [22]
    LIU T, KOU Z, LU J, et al. Preparation of superhard cubic boron nitride sintered from commercially available submicron powders [J]. Journal of Applied Physics,2017,121(12):125902. doi: 10.1063/1.4979312
    [23]
    YIN X, KOU Z, WANG Z, et al. Micro-sized polycrystalline cubic boron nitride with properties comparable to nanocrystalline counterparts [J]. Ceramics International,2020,46(7):8806-8810. doi: 10.1016/j.ceramint.2019.12.120
    [24]
    ZHAO M, KOU Z, ZHANG Y, et al. Superhard transparent polycrystalline cubic boron nitride [J]. Applied Physics Letters,2021,118(15):151901. doi: 10.1063/5.0045545
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(10)

    Article Metrics

    Article views (94) PDF downloads(6) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return